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Topic: Nitrous Acid Reaction Verification  (Read 3349 times)

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Offline antelope

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Nitrous Acid Reaction Verification
« on: December 09, 2013, 10:22:47 AM »
Hi! So here is the reaction for the nitrous acid test. I tried demonstrating the mechanism for the reaction below but I think I went wrong somewhere. Could someone please clarify where I went wrong. Beta-Naphthol should give an intense orange red colour after the reaction is complete.




Offline Hunter2

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Re: Nitrous Acid Reaction Verification
« Reply #1 on: December 09, 2013, 12:33:58 PM »
It looks for me ok, only Cr I dont know why you wrote it beside the Nitrogens.

Offline antelope

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Re: Nitrous Acid Reaction Verification
« Reply #2 on: December 09, 2013, 12:51:32 PM »
That was just put there to imply that a compound containing chromium reacts with the aryldiazonium ion.

Offline opsomath

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Re: Nitrous Acid Reaction Verification
« Reply #3 on: December 09, 2013, 02:27:39 PM »
No it's not, I think rather that someone meant to write "Cl" instead of "Cr." :)

Offline antelope

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Re: Nitrous Acid Reaction Verification
« Reply #4 on: December 09, 2013, 05:00:32 PM »
Ah yes, you're right. Well is the chlorine meant to be even attached to the nitrogen?

Offline opsomath

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Re: Nitrous Acid Reaction Verification
« Reply #5 on: December 10, 2013, 10:31:51 AM »
No, it is only the counterion. Here is the crystal structure of the solid form:

http://upload.wikimedia.org/wikipedia/commons/e/e5/Benzenediazonium-chloride-xtal-3D-vdW.png

As you can see, the chloride ions kind of stack in T-shaped configuration relative to the N-N bond.

Offline antimatter101

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Re: Nitrous Acid Reaction Verification
« Reply #6 on: December 20, 2013, 01:07:12 AM »
Three keywords:

Arenediazonium salts
Azo compounds
Sandmeyer reaction

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