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Topic: Enthalpy of formation question  (Read 1942 times)

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Offline tg22542

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Enthalpy of formation question
« on: January 29, 2014, 02:34:06 PM »
The enthalpy of combustion (ΔH°c) of 2-pentanol (C5H12O) is -3315.40 kJ/mol. Using the appropriate information given below, calculate the enthalpy of formation (ΔH°f), in kJ/mol, for 2-pentanol


My attempt :

2C5H12O + 15O2 -> 10CO2 + 12H2O

ΔHrx = [(10* -393.51) + (12*-285.83)] - (2*ΔHf)

ΔHf = [[(10* -393.51) + (12*-285.83)] - (-3315.4)] /2

= -2023.0 kJ/mol


Why is this incorrect? I have no idea what I'm doing wrong..

Offline Corribus

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Re: Enthalpy of formation question
« Reply #1 on: January 29, 2014, 03:09:43 PM »
I'm not sure what you're off by, but enthalpy of combustion is defined as the amount of energy to burn 1 mole of your starting material to completion. Are you basing your calculation off of 1 mole of 2-pentanol?
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline tg22542

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Re: Enthalpy of formation question
« Reply #2 on: January 29, 2014, 03:14:00 PM »
Yup.. and that would be my problem haha.. Whoops

Thank you!

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