October 31, 2024, 07:36:04 PM
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Topic: Can I do this with grignard?  (Read 1534 times)

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Offline darkdevil

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Can I do this with grignard?
« on: March 31, 2014, 09:34:04 AM »
Hi,
I wonder if I can make this ketone with grignard condition with acryloyl chloride? And then make a polymer with BPO as radical initiator? My concern is that if the double would be attacked by the carbanion in gridgnard reaction?


Offline magician4

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Re: Can I do this with grignard?
« Reply #1 on: March 31, 2014, 10:02:50 AM »
if you try to work with low stationary grignard-conc. (i.e. add the grignard dropwise to an excess of acryloyl chloride, to suppress secondary reaction at the keto-function), and evapotate excess acryloyl chloride off in the end, this should work

regards

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