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Topic: Finding the pH of saturated Ca(OH)2  (Read 17620 times)

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hester4

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Finding the pH of saturated Ca(OH)2
« on: March 19, 2006, 03:09:08 PM »
Calcium hydroxide Ca(OH)2, is the cheapest strong base available. It is generally used for industrial operations in which a high concentration of OH-is not required. Ca(OH)2(s) is soluble in water only to the extent of 0.16 g Ca(OH)2/100.0 mL at 25 0C. What is the pH of saturated Ca(OH)2(aq) at 250C?

OK, here is what I did:

40.08 + (16.00 x 2) + (1.008 x 2)=74.096

1mol Ca(OH)2 / 74.096g Ca(OH)2 x 0.16g Ca(OH)2 / 100mL x 1000mL / 1L

After you do the math for that equation, you come up with: 0.02159, this is the OH- concentration.

pOH = -log(OH) pOH = -log(0.02159) = 1.666

pH + pOH = 14.00

We have the OH, so pH = 14.00 - pOH pH = 14.00 - 1.666

pH = 12.334 = 12.3

Here is my question, (it's probably a stupid one), when I am finding the OH- concentration, do I multiply 0.02159 by 2?

Isn't the balanced equation: Ca(OH)2 <> Ca(2+) + 2OH-?

If I did that, the answer would come out to be 12.6.  Both of these answers are choices on my homework (multiple choice).  Any help is appreciated and if I am doing anything else wrong please let me know.

Offline Borek

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Re:Finding the pH of saturated Ca(OH)2
« Reply #1 on: March 19, 2006, 03:36:40 PM »
Here is my question, (it's probably a stupid one), when I am finding the OH- concentration, do I multiply 0.02159 by 2?

Isn't the balanced equation: Ca(OH)2 <> Ca(2+) + 2OH-?

Yes, yes.
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Offline Albert

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Re:Finding the pH of saturated Ca(OH)2
« Reply #2 on: March 19, 2006, 03:37:33 PM »
when I am finding the OH- concentration, do I multiply 0.02159 by 2?

Isn't the balanced equation: Ca(OH)2 <> Ca(2+) + 2OH-?

If I did that, the answer would come out to be 12.6.  Both of these answers are choices on my homework (multiple choice).  Any help is appreciated and if I am doing anything else wrong please let me know.


Yes, indeed. The right answer is 12.64.

hester4

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Re:Finding the pH of saturated Ca(OH)2
« Reply #3 on: March 19, 2006, 03:43:32 PM »
Thank you guys very much.

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