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Topic: Isomers  (Read 4021 times)

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Offline Plumbum

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Isomers
« on: September 23, 2014, 06:29:45 AM »
I am supposed to draw all possible isomers of [CoCl2(en)2]3+

I can only think of s configurational isomer such as cis/trans .. The other isomers don't fit here in my opinion. Can anyone help?
There might be some language misunderstandings - I'm from Germany

Offline Dan

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Re: Isomers
« Reply #1 on: September 23, 2014, 08:06:24 AM »
What types of stereoisomerism do you know?
My research: Google Scholar and Researchgate

Offline Plumbum

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Re: Isomers
« Reply #2 on: September 23, 2014, 09:03:09 AM »
Inosisation isomer
Hydration isomer
Coordination isomer
And I don't know the translation but the isomer where the binding is different like with NO2  Or cn

For me none of them apply to the example
There might be some language misunderstandings - I'm from Germany

Offline Dan

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Re: Isomers
« Reply #3 on: September 23, 2014, 09:21:54 AM »
OK, but focus on stereochemistry - ie same atom connectivity but different spatial arrangement.

What types of stereoisomers do you know about?
My research: Google Scholar and Researchgate

Offline Plumbum

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Re: Isomers
« Reply #4 on: September 23, 2014, 09:33:18 AM »
Enantiomer and diastereomer

You distinguish between cis and trans and an octaeder also has fac or mer.

A Tetrahedra doesn't have cis or trans.

Do you mean that?
There might be some language misunderstandings - I'm from Germany

Offline Dan

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Re: Isomers
« Reply #5 on: September 23, 2014, 01:27:42 PM »
Yes. Are any of the isomers you have identified chiral?
My research: Google Scholar and Researchgate

Offline Plumbum

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Re: Isomers
« Reply #6 on: September 23, 2014, 02:44:44 PM »
Oh yeah! I forgot to mention enantioners are chiral. Diastereomer are not.
There might be some language misunderstandings - I'm from Germany

Offline sjb

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Re: Isomers
« Reply #7 on: September 23, 2014, 04:25:10 PM »
Oh yeah! I forgot to mention enantioners are chiral. Diastereomer are not.

Are you sure?

Offline Plumbum

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Re: Isomers
« Reply #8 on: September 23, 2014, 04:46:46 PM »
I thought I am sure my professor told us so
There might be some language misunderstandings - I'm from Germany

Offline Dan

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Re: Isomers
« Reply #9 on: September 24, 2014, 01:35:33 PM »
I thought I am sure my professor told us so

Unlikely, it is not necessarily true - you should look up the definitions.

Back to the specific question you asked - draw out the isomers of CoCl2(en)2 you can think of (this is cis and trans right?).

Are either of those chiral?
My research: Google Scholar and Researchgate

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