April 27, 2024, 03:54:43 PM
Forum Rules: Read This Before Posting


Topic: Lanthanide stability  (Read 1800 times)

0 Members and 1 Guest are viewing this topic.

Offline Pico

  • New Member
  • **
  • Posts: 6
  • Mole Snacks: +0/-0
Lanthanide stability
« on: October 13, 2014, 12:39:06 AM »
What is the periodic trend in Ln stability, and how can the Ln3+ ions be separated from each other?

Offline kriggy

  • Chemist
  • Sr. Member
  • *
  • Posts: 1520
  • Mole Snacks: +136/-16
Re: Lanthanide stability
« Reply #1 on: October 13, 2014, 04:34:26 PM »
Basicaly all of them are stable in +III oxidation state. +IV and +II are also quite common. Do you have any specific compounds in mind?
Separation is difficult because they have very similar chemical properties. Fraction crystalization was used in a past (I heard that one guy did over 1500 crystalizations to get the pure element). Today extraction or chromatography is used. Look at wikipedia its all there - unless you want specifics, then I suggest some peer-rewieved journals or other literature (maybe chemistry of elements?)

Sponsored Links