[STM]

I recently synthesized methyl hydroperoxide (MHP) in an aqueous medium. I need to extract the MHP from the reaction mixture by extracting it into diethyl ether and back-extracting it into water. The procedures I saw just mentioned that the ether is boiled-off.
Please what do you understand by the term "boil-off"? Does it mean that I place the ether extract in a flask,add some water to it, immerse it in an electric water bath and heat to about 50 degrees Celsius  in a fume cupboard and let the ether go away without necessarily recovering it by distillation? Please provide clarifications on what is meant by boiling-off the ether or on the procedure for back-extracting into water. I will appreciate any link that provides further information.

Thank you

[discodermolide]

Boil off sound in your case more like blow up.
Just extract into water and use a separating funnel to remove the ether.
Be careful, do not isolate any solid material it may explode.

[STM]

@discodermolide: Thank you for your response. So there will be no need for any attempt to drive off the diethyl ether. I was wondering if the octanol:water partition coefficient of Methyl Hydroperoxide is low enough to make it prefer migration into the aqueous phase than staying in the organic phase. I was wondering if i wont be leaving behind a concentrated MHP in an ether layer. Please comment.

Thank you

[discodermolide]

I have no idea of its aqueous solubility nor the partition coefficient. This information should be available, Google it.