No idea, it doesn't follow form the question. Also the final answer is wrong, it should be 31.8 mL, not 318 mL.
In general 0.250 looks like a volume, but it is not the volume given in the problem. Plus, it cancels out, so it doesn't matter. But as there is a trivial math error in the final answer, I don't see why there can't be a trivial mistake in the formula used.