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Topic: Free Energy Change and Gas Quotient  (Read 2972 times)

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Offline Sis290025

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Free Energy Change and Gas Quotient
« on: April 13, 2006, 06:44:41 AM »
Is my final answer correct?

Determine the free energy change associated with the formation of methanol from carbon monoxide and hydrogen gas if the partial pressure of CO is 1.0700 atm, H2 is 2.2800 atm, and CH3OH is 0.0600 atm at 298K. The standard free energy of formation for methanol is - 24.70 kJ. Give your answer in kilojoules.

CO (g) + 2H2 (g) --> CH3OH (g)

deltaG* = -24.70 kJ = -24,700 J

deltaG = G* + RTlnQ

Q = [(CH3O)]/[(CO)*(H2)^2] = [0.06 atm]/[(2.28 atm)^2*(1.07 atm)]
= 0.010786928

delta G = -24,700 J + (298 K)(8.314)ln(0.010786928)
= -35921.965 J
= -35.92 kJ

Thanks.






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