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Topic: Use activities to calculate the molar solubility  (Read 8109 times)

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Offline johnnyjohn993

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Use activities to calculate the molar solubility
« on: July 17, 2015, 03:42:43 AM »
Use activities to calculate the molar solubility of Zn(OH)2 in 0.0200M KCl
Ksp for Zn(OH)2 = 3.00x10-16 at 25°C
 
μ =1/2((0.0200×(1)2)+(0.0200x(-1)2))
μ= 0.0200M

given φx, nm
OH- 0.35nm
Zn2+ 0.6nm

Invoking the Debye-Huckle equation in order to find the activity coefficient of the ions at a given μ.
-logγZn2+=                                     0.51x22xsqrt(0.0200)
                                           ______________________________
                                                1+ 3.3(0.6)xsqrt(0.0200)

γZn2+=  0.595

-logγOH-1=                                      0.51x(-1)2xsqrt(0.0200)
                                          ______________________________
                                                  1+ 3.3(0.35)xsqrt(0.0200)

γOH-1=0.867

Using the formula
Ksp =K'sp x (γZn2+)(γOH-1)2

K'sp =       3.00x10-16
              ______________________
               (0.595) (0.867)2

K'sp=     6.71x10-10

 Zn(OH)2  ::equil:: Zn2+  + 2OH-

K'sp=  s*(2s)2

 2.06x10-15=  4s3

s= 5.5x10-4 mol/L 


But the answer here is 5.5x10-6 mol/L please help me see my mistakes.

Offline mjc123

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Re: Use activities to calculate the molar solubility
« Reply #1 on: July 17, 2015, 03:54:54 AM »
You divide 3e-16 by a quantity equal to 0.447 and get 6.71e-10! So s3 is out by a factor of 106, and s by a factor of 100.

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