Use activities to calculate the molar solubility of Zn(OH)2 in 0.0200M KCl
Ksp for Zn(OH)
2 = 3.00x10
-16 at 25°C
μ =1/2((0.0200×(1)
2)+(0.0200x(-1)
2))
μ= 0.0200M
given φ
x, nm
OH
- 0.35nm
Zn
2+ 0.6nm
Invoking the Debye-Huckle equation in order to find the activity coefficient of the ions at a given μ.
-logγ
Zn2+= 0.51x2
2xsqrt(0.0200)
______________________________
1+ 3.3(0.6)xsqrt(0.0200)
γ
Zn2+= 0.595
-logγ
OH-1= 0.51x(-1)
2xsqrt(0.0200)
______________________________
1+ 3.3(0.35)xsqrt(0.0200)
γ
OH-1=0.867
Using the formula
Ksp =K'sp x (γ
Zn2+)(γ
OH-1)
2K'sp = 3.00x10
-16 ______________________
(0.595) (0.867)
2K'sp= 6.71x10
-10 Zn(OH)
2 Zn
2+ + 2OH
-K'sp= s*(2s)
2 2.06x10
-15= 4s
3s= 5.5x10
-4 mol/L
But the answer here is 5.5x10
-6 mol/L please help me see my mistakes.