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Topic: Thermograph  (Read 1807 times)

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Offline lrisNil

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Thermograph
« on: February 14, 2016, 04:03:23 AM »
A solid sample initially contains a mixture of CaC2O4 and CaCO3.
CaC2O4 decomposes around 500 °C and CaCO3 decomposes around 700 °C

This TGA graph plots the mass of solid remaining as the sample temperature is raised range 350 to 800 °C .

What is the mass percent of calcium carbonate in the original mixture?

First I wrote the chemical equations:
CaC2O4 ----> CaCO3 + CO
CaCO3 ----> CaO + CO2

And I see that the first drop from 9.1mg to 7.8mg is about 1.3mg drop.
So that means the CO escaped and there can only be CaCO3 left I think.
So then I did 7.8/9.1 *100 but this answer is incorrect.

Any help appreciated, I'm super confused.
Iris Lin

Offline Borek

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Re: Thermograph
« Reply #1 on: February 14, 2016, 09:21:52 AM »
CaCO3 produced during the decomposition doesn't count as CaCO3 originally present in the sample.

If there were 1.3 mg of CO produced, how many mg of oxalate decomposed? (Assuming your decomposition reaction is a correct one, no idea if it is, even if it looks plausible.)
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