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Offline BME_Dev

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Help with combustion problem
« on: January 19, 2017, 04:19:05 PM »
I haven't taken a Chem. course since fall 2015 so I'm having trouble with remembering a few things. One of which is a combustion problem, if anyone could help me figure it out I would greatly appreciate.
PROBLEM: An 4.64 g sample of a compound with the formula C3H6O2 was combusted in oxygen producing CO2 and H2O What mass of H2O will be formed?

Thanks in advance.

Offline AWK

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Re: Help with combustion problem
« Reply #1 on: January 19, 2017, 06:37:00 PM »
Start from a balanced reaction.
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Offline BME_Dev

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Re: Help with combustion problem
« Reply #2 on: January 19, 2017, 07:36:19 PM »
That's the only part of the problem I remember to do, everything after that is really what I'm lost on. Tried searching google, but no luck. Thank you

Offline BME_Dev

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Re: Help with combustion problem
« Reply #3 on: January 19, 2017, 07:56:33 PM »
H2O mass = 3.88 grams.

Offline Arkcon

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Re: Help with combustion problem
« Reply #4 on: January 19, 2017, 07:58:47 PM »
OK, lets see that balanced reaction.  Do you know how you will use it?  Do you know the units of a balanced chemical equation, and how to convert units you have to units you need.

Sorry to answer a question with a question, but that's what we do here.  That's detailed in  the  Forum Rules{click}.  You agreed to follow these rules when you signed up.

If you need, "Just everything" you'll find it in your textbook.  If you know some bits, but want to tell us one post at a time, this will be a tedious thread.  If you just want to assure us you know something, and not show it to us, this will be a completely pointless thread.
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline AWK

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Re: Help with combustion problem
« Reply #5 on: January 19, 2017, 08:05:10 PM »
AWK

Offline BME_Dev

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Re: Help with combustion problem
« Reply #6 on: January 20, 2017, 04:21:43 AM »
Well, here's my work so maybe this will help clarify what I asking. The reason I put 3.88 grams was because the problem stated to give three significant figures. To better state my question(s): I know the answer is correct because I got full credit for it, but I didn't feel comfortable with how I achieved it as I had to rearrange the labeling multiple times. With that being said, I was wondering if my set up is correct? Furthermore, I feel as if the time it took to actually solve the problem from start to beginning was incredibly longer than it should've been. Would anyone recommend a way I can shorten any part of the process to achieve my answer?

NOTE: What's in the top right corner is a table I use to keep track of elements when balancing. My work starts in top left corner and is going in order. I apologize in advance for my sloppy 2nd grade hand writing. As well, feedback would be greatly appreciated.


http://m.imgur.com/a/LtLOd
« Last Edit: January 20, 2017, 07:53:37 AM by Borek »

Offline AWK

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Re: Help with combustion problem
« Reply #7 on: January 20, 2017, 04:44:57 AM »
Only balancing OK
2C3H6O2 + 7O2 = 6CO2 + 6H2O
Now simplify extracting only balancing hydrogen atoms
C3H6O2  :rarrow: 3H2O
74.0784  :rarrow: 54.0444
Without calculation you can estimate result as ~5/7 ≈ ~70 % of your sample
AWK

Offline Borek

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Re: Help with combustion problem
« Reply #8 on: January 20, 2017, 08:04:29 AM »
Several problems with what you did.

You tried to apply a unit conversion scheme, but you were not consistent with the units. Mol of C3H6O2 doesn't cancel out with mol of H2O.

You have never calculated molar mass of the substance that was burnt, and that should be the next step after balancing.

108.1g/mol is not a molar mass of 6 moles of water, no such thing. Molar mass is always mass of a single mole. 108.1 g is a MASS of 6 MOLES of water.

I guess you answer was accepted accidentally - the correct one is very similar.

ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline BME_Dev

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Re: Help with combustion problem
« Reply #9 on: January 20, 2017, 04:37:12 PM »
Didn't notice that I put it only per 1 mol. AWK, your explanation worked as well and was put in a simpler way, thank you. Borek, what answer did you get and what did you do differently than I did to reach it? Not saying you're wrong, just curious.

Offline Borek

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Re: Help with combustion problem
« Reply #10 on: January 20, 2017, 05:25:53 PM »
3.38 g is a correct answer, and I have not bothered with manual calculations.

There are many ways to calculate the final answer. The one you selected (unit conversion) is as good as any if applied correctly. I told you what is wrong with your approach. Your answer is not 3.88 g of water, but [itex]3.88 \frac {mol C_3H_6O_2}{mol H_2O}[/itex] (whatever it means).

Basically you should start with finding number of moles of the burnt substance, convert it to the number of moles of water, then convert number of moles of water to the mass of water.

AWK's approach is a convenient shortcut which shouldn't be used blindly before you become fluent in a standard approach (at which stage the shortcut will be obvious).
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline BME_Dev

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Re: Help with combustion problem
« Reply #11 on: January 20, 2017, 06:14:50 PM »
Okay, thanks for your help man. Greatly appreciated.

Offline AWK

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Re: Help with combustion problem
« Reply #12 on: January 20, 2017, 08:37:45 PM »
4.64*3*H2O/C3H6O2 = 3.385(14352361822)
AWK

Offline Borek

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Re: Help with combustion problem
« Reply #13 on: January 21, 2017, 03:53:48 AM »
H2O/C3H6O2

You could at least explain you mean ratio of molar masses here, unless you are trying to win "the most cryptic answer" competition.
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Offline AWK

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Re: Help with combustion problem
« Reply #14 on: January 21, 2017, 03:57:15 AM »
Quote
I explained it previously
Quote
Now simplify extracting only balancing hydrogen atoms
C3H6O2  :rarrow: 3H2O
74.0784  :rarrow: 54.0444
I used calculator that directly replace formulas by masses (it use the most exact atom masses by IUPAC)
http://www.periodni.com/scientific_calculator.html
This is a copy from notebook of calculator (history of calculations) with brackets inserted by me.
4.64*3*H2O/C3H6O2 = 3.385(14352361822)
« Last Edit: January 21, 2017, 06:32:57 AM by AWK »
AWK

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