Is this a homework assignment, or are you working in a laboratory trying to prepare this? Clearly your initial calculation is incorrect, but it would be very helpful if you would show all of your work so far. You can check the pH values of some substances at various concentrations in books such as The Chemist's Companion, for example. One other point that I would like to mention is that when one describes a 0.10 molar acetate buffer, the value of 0.10 M refers to the sum of the concentrations of conjugate acid and conjugate base.