what is meant by polar and non-polar? what's the relation between polar and symmetry or non-symmetry?
A dipole moment is an uneven distribution of charge. If a molecule has a dipole moment it is polar.
So, HCl (gas) is polar because it has a dipole moment.
However, a molecule with several polar bonds is non-polar if the dipole moments cancel out by symmetry.
For example, CO
2 is not polar. The C-O bonds are polar bonds, but because CO
2 is linear, the dipoles of the bonds exactly cancel each other out, and there is no
overall dipole moment.
Water is polar. The O-H bonds are polar, but the bent geometry of the molecule means that there is an overall dipole moment.