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Topic: 3-chloropropyne and furan reaction  (Read 1104 times)

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Offline dolphinsea14

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3-chloropropyne and furan reaction
« on: April 24, 2019, 08:20:19 AM »
What are the products of the reaction between 3-chloropropyne and furan?

Offline rolnor

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Re: 3-chloropropyne and furan reaction
« Reply #1 on: April 24, 2019, 09:32:33 AM »
What do you think, Diels Alder or some other cycloaddition?

Offline dolphinsea14

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Re: 3-chloropropyne and furan reaction
« Reply #2 on: April 24, 2019, 10:11:31 AM »
I don't know, it was a question on a test. I'm not sure if substitution or Diels Alder reaction will happen. Is it possible to have Diels-Alder with 3-chloropropyne? Is it a good dienophile? I thought substitution was more probable, but since it is chloroALKYNE, I'm not so sure...

Offline OrganicDan96

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Re: 3-chloropropyne and furan reaction
« Reply #3 on: April 24, 2019, 10:25:54 AM »
I don't know, it was a question on a test. I'm not sure if substitution or Diels Alder reaction will happen. Is it possible to have Diels-Alder with 3-chloropropyne? Is it a good dienophile? I thought substitution was more probable, but since it is chloroALKYNE, I'm not so sure...

what product would a substitution reaction using furan look like do you think?

Offline dolphinsea14

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Re: 3-chloropropyne and furan reaction
« Reply #4 on: April 24, 2019, 10:37:44 AM »
I thought 2-propynylfuran https://pubchem.ncbi.nlm.nih.gov/compound/54025313
If the chlorine is substitued...

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